• 文献标题:   Colorimetric Detection of Antioxidants in Food Samples Using MnO2/Graphene Quantum Dot Composites with Oxidase-like Activity
  • 文献类型:   Article
  • 作  者:   FACURE MHM, ANDRE RS, MERCANTE LA, CORREA DS
  • 作者关键词:   nanozyme, optical sensor, oxidasemimetic activity, manganese dioxide, graphene quantum dot, food analysi
  • 出版物名称:   ACS APPLIED NANO MATERIALS
  • ISSN:  
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.1021/acsanm.2c03340 EA SEP 2022
  • 出版年:   2022

▎ 摘  要

Recently, strategies for developing colorimetric sensors relying on nanozymes for the detection of analytes of health, food, and environmental interest have gained significant importance. Herein, a rapid and sensitive colorimetric assay based on manganese dioxide/graphene quantum dot (MnO2/GQD) composites was developed for the detection of antioxidants in food. The composite, synthesized by a hydrothermal method, served as a nanozyme with outstanding oxidase-like catalytic activity to trigger the 3,3 ',5,5 '-tetramethybenzidine (TMB) chromogenic reaction. Then, an assay was performed to evaluate the reducing ability of antioxidants toward oxTMB by detecting color changes during the procedure. The colorimetric method achieved high selectivity and sensitivity toward the detection of gallic acid, tannic acid, and ascorbic acid with detection limits (S/N = 3) of 0.07, 0.28, and 0.69 mu mol L-1, respectively. Moreover, the assay was used to accurately measure and discriminate the antioxidants in real food samples, revealing its great promise for portable and rapid food analysis.