• 文献标题:   Magnetite modified graphene nanosheets with improved rate performance and cyclic stability for Li ion battery anodes
  • 文献类型:   Article
  • 作  者:   ZAI JT, YU C, ZOU Q, TAO LQ, WANG KX, HAN QY, LI B, XIAO YL, QIAN XF, QI RR
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Shanghai Jiao Tong Univ
  • 被引频次:   17
  • DOI:   10.1039/c2ra20319g
  • 出版年:   2012

▎ 摘  要

Magnetite modified graphene nanosheets (MGNSs) were synthesized through a simple ultrasonic method, electrochemical performances indicated that the obtained MGNSs exhibited remarkably high reversible lithium storage capacity (1235 mAh g(-1) after 50 cycles at 0.2 A g(-1)), good rate capability (315 mAh g(-1) at 10 A g(-1)) and improved cycling stability (450 mAh g(-1) after nearly 700 cycles at 5 A g(-1)). The improved electrochemical performances of the obtained MGNSs could be attributed to its inherent electronic conductivity, excellent mechanical properties and expanded (002) interlayer spacing of GNSs. Furthermore, magnetite nanoparticles anchored onto graphene nanosheets (GNSs) could serve as spacers to reduce the stack/restack of GNSs during charge-discharge process and improve their electrochemical performances as anode materials for lithium-ion batteries (LIBs).