• 文献标题:   Improved mechanical performance of bisphenol-A graphene-oxide nano-composites
  • 文献类型:   Article
  • 作  者:   BANSAL SA, SINGH AP, KUMAR A, KUMAR S, KUMAR N, GOSWAMY JK
  • 作者关键词:   epoxy, graphene oxide, nanocomposite, nanoindentation, elastic modulu, hardnes, fracture resistance
  • 出版物名称:   JOURNAL OF COMPOSITE MATERIALS
  • ISSN:   0021-9983 EI 1530-793X
  • 通讯作者地址:   Panjab Univ
  • 被引频次:   9
  • DOI:   10.1177/0021998317741952
  • 出版年:   2018

▎ 摘  要

Epoxy resins have been extensively utilized for mechanical strength applications in the field of aerospace, automobiles, marine, defence, etc. Improving the strength as well as fracture behaviour of the light weight materials is challenging. Present work is an attempt to enhance elastic modulus, hardness and fracture resistance simultaneously by reinforcing the epoxy (bisphenol-A) matrix with a new-age two-dimensional atomically thin graphene oxide filler. Wet chemical oxidation method was used to prepare graphene oxide sheets. Morphological study of the synthesized graphene oxide was carried out using scanning electron microscopy. Fourier-transformed infrared, ultraviolet-visible and Raman spectroscopic techniques were also employed to ascertain the synthesis of graphene oxide. The results confirmed the synthesis of well oxidized graphene oxide sheets. The prepared graphene oxide sheets were then sonicated in acetone solution to ensure better dispersion in the bisphenol-A graphene oxide nano-composite using 0.25, 0.5, 1.0 and 1.5wt.% graphene oxide reinforcement. Solution mixing method was used to synthesize the polymer nano-composite. Scanning electron microscopy results revealed the smooth dispersion of graphene oxide in the bisphenol-A matrix. Nano-indentation of the bisphenol-A graphene oxide nano-composite showed a considerable jump in elastic modulus at 1wt.% and hardness at 0.50wt.% of graphene oxide reinforcement. Fracture resistance of bisphenol-A graphene oxide composite as represented by ratio of elastic modulus to hardness was enhanced by 24% as compared to the pristine bisphenol-A. Our results demonstrate a promising way to improve the mechanical characteristics of epoxy resins through graphene oxide reinforcement at low weight percentages.