• 文献标题:   Monodisperse Au-Pd bimetallic alloyed nanoparticles supported on reduced graphene oxide with enhanced electrocatalytic activity towards oxygen reduction reaction
  • 文献类型:   Article
  • 作  者:   LV JJ, LI SS, WANG AJ, MEI LP, CHEN JR, FENG JJ
  • 作者关键词:   aupd nanoparticle, reduced graphene oxide, oxygen reduction reaction, methanol tolerance
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Zhejiang Normal Univ
  • 被引频次:   70
  • DOI:   10.1016/j.electacta.2014.05.138
  • 出版年:   2014

▎ 摘  要

In this work, a simple and facile strategy was developed for preparation of well-defined Au-Pd bimetallic alloyed nanoparticles uniformly supported on reduced graphene oxide nanosheets (RGOs) under solvothermal conditions. The detailed morphology, crystal structure, and composition were well characterized by (high-resolution) transmission electron microscopy (TEM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). The as-prepared nanocomposites displayed the enhanced catalytic ability, better stability, and good methanol tolerance towards oxygen reduction reaction (ORR) in alkaline media, compared with commercial Pd black and RGOs (reduced by NaBH4) catalysts. The as-developed method could be applied for synthesis of other morphology-controlled bimetallic electrocatalysts. (C) 2014 Elsevier Ltd. All rights reserved.