• 文献标题:   Microwave reduction of graphene oxide
  • 文献类型:   Review
  • 作  者:   JAKHAR R, YAP JE, JOSHI R
  • 作者关键词:   microwave heating, reduced graphene oxide, graphene
  • 出版物名称:   CARBON
  • ISSN:   0008-6223 EI 1873-3891
  • 通讯作者地址:   Univ New South Wales
  • 被引频次:   2
  • DOI:   10.1016/j.carbon.2020.08.034
  • 出版年:   2020

▎ 摘  要

The reduction of Graphene Oxide (GO) has become the widely accepted route to obtain graphene like materials for bulk scale production. The commonly used methods of reduction include chemical and thermal routes. But these processes often demand the use of toxic chemicals or exposure to high temperatures for prolonged time that leads to a higher cost of production. In recent years, many nonchemical reduction methods have garnered attention and microwave reduction has emerged as a suitable alternative due to its accelerated and volumetric heating approach. Graphene owing to the presence of pi electrons in its structure is a good microwave absorber, but upon oxidation the oxygen functional groups on graphene make it insulating and unresponsive to microwaves. This paper reviews some non-chemical reduction techniques, the mechanism of microwave heating and provides a comprehensive account of microwave reduction of GO organized in two main categories: (i) solid state microwave reduction and (ii) solvent assisted microwave reduction. Additionally, the methods to improve microwave reduction which also covers the concept of hybrid microwave heating are elucidated in detail. We believe that microwave reduction of GO has the potential for mass scale production of graphene-based materials. (C) 2020 Elsevier Ltd. All rights reserved.