• 文献标题:   Synthesis and properties of Ce-doped TiO2-reduced graphene oxide nanocomposite
  • 文献类型:   Article
  • 作  者:   AHMADI N, NEMATI A, BAGHERZADEH M
  • 作者关键词:   cedoped titania, graphene, synergistic effect, photoelectric activity, electrical conductivity
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   Sharif Univ Technol
  • 被引频次:   7
  • DOI:   10.1016/j.jallcom.2018.01.105
  • 出版年:   2018

▎ 摘  要

A nanocomposite of Ce-doped TiO2-reduced graphene oxide (CedT/RGO) was synthesized to evaluate the synergistic effects of constituents on electrical and photoelectric properties. The nanoparticles of titania and CedT were synthesized via the sol-gel method. Then, RGO was prepared using a new version derived from the Hammer's method and hydrothermal methods. Finally, CedT/RGO nanocomposite was synthesized applying hydrothermal method. The nanoparticles and nanocomposite were characterized by Xray diffraction, Fourier transform infrared spectroscopy, Field emission scanning electron microscopy (FESEM), Energy dispersive X-ray spectroscopy and elemental mapping. Then, diffuse reflectance and photoluminescence spectroscopy were conducted to study photoelectric and photoluminescence behavior. Finally, electrical conductivity measurement showed that the electrical conductivity of CedT/RGO nanocomposite was increased from 4.6 (mu S/cm) to 81.3 (mu S/cm). In addition, the absorption spectrum of the nanocomposite was shifted toward visible wavelengths. The band gap of the titania was reduced from similar to 3.2 eV to similar to 2.65 eV in CedT nanoparticles and it was further reduced to similar to 1.95 eV in the CedT/RGO nanocomposite. The FESEM results of the nanocomposite indicated the formation of CedT nanoparticles, smaller than 50 nm, on the RGO sheets. These data indicate that this nanocomposite can be suitable for electrical, photoelectric, photocatalytic and sensing applications. (c) 2018 Published by Elsevier B.V.