• 文献标题:   Lanthanum sulfide-manganese sulfide/graphene oxide (La2S3-MnS/GO) composite thin film as an electrocatalyst for oxygen evolution reactions
  • 文献类型:   Article
  • 作  者:   MANE VJ, KALE SB, UBALE SB, LOKHANDE VC, PATIL UM, LOKHANDE CD
  • 作者关键词:   composite, graphene oxide, lanthanum sulfidemanganese sulfide, oxygen evolution reaction
  • 出版物名称:   JOURNAL OF SOLID STATE ELECTROCHEMISTRY
  • ISSN:   1432-8488 EI 1433-0768
  • 通讯作者地址:  
  • 被引频次:   4
  • DOI:   10.1007/s10008-021-04945-7 EA APR 2021
  • 出版年:   2021

▎ 摘  要

In this study, the lanthanum sulfide-manganese sulfide (La2S3-MnS) nanosheet composite films with different thicknesses were grown on graphene oxide (GO) (LMS/GO) coated stainless steel substrate using binder-free successive ionic layer adsorption and reaction (SILAR) method, for the first time. The formation of crystal structure and chemical states was identified using X-ray diffraction analysis and X-ray photoelectron spectroscopy, respectively. The nitrogen sorption analysis showed the micro-/mesoporous structure of La2S3-MnS-90/GO thin film exhibiting a specific surface area of 170 m(2) g(-1) and hydrophilic nature. The scanning electron microscopic image showed microstructure with porous ultrathin interconnected nanosheets. Surface texture was examined using transmission electron microscopy. The resulting La2S3-MnS-90/GO thin film electrocatalyst showed oxygen evolution reaction (OER) overpotential as low at 263 mV to reach 10 mA cm(-2) current density with Tafel slope of 48 mV dec(-1) for in 1 M KOH solution and stability over 50 h. Consequently, it could be considered one of the alternate sulfide-based catalysts for highly efficient OER evolution.