• 文献标题:   Addition of Ce in Cu/Three-Dimensional Graphene Derived from Watermelon for Low Temperature NH3-SCR
  • 文献类型:   Article
  • 作  者:   KANG Y, LI ZF, CUI JX, GENG C, ZHANG C, LI P, YANG CL
  • 作者关键词:   ce, cu, nh3scr, nitrogen oxide, 3dimensional graphene
  • 出版物名称:   CHEMISTRYSELECT
  • ISSN:   2365-6549
  • 通讯作者地址:   Qiqihar Univ
  • 被引频次:   0
  • DOI:   10.1002/slct.201904519
  • 出版年:   2020

▎ 摘  要

In this paper, 3-Dimensional Graphene (3DG) prepared by watermelon was used as the supporter to synthesize Cu/3DG, Ce/3DG and Cu-Ce/3DG catalysts by the hydrothermal method, after which they were also investigated in NH3-SCR. Synergistic mechanism between Ce and Cu was further explored. Experimental results indicated that the three catalysts all exhibited excellent low-temperature nitrogen oxide reduction activity which reached 99 % and remained unchanged in the range of 250-400 degrees C. 2Cu-3Ce/3DG displayed optimal NOx conversion rate, namely, its activity reached 92.9 % at 200 degrees C that mainly attributed to the increase of the Cu+, Ce3+ and the form of the abundant acid sites. Moreover, the sulfur and water resistance of 2Cu-3Ce/3DG were tested. At 250 degrees C, the conversion rate of NOx was increased to 99.1 %, which showed excellent sulfur resistance.