• 文献标题:   Functionalized bioinspired porous carbon with graphene sheets as anode materials for lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   IMTIAZ M, ZHU CL, LI Y, PAK M, ZADA I, BOKHARI SW, CHEN ZX, ZHANG D, ZHU SM
  • 作者关键词:   bioinspired porous carbon, bagasse, nitric acid treatment, graphene, lithiumion battery
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   Shanghai Jiao Tong Univ
  • 被引频次:   9
  • DOI:   10.1016/j.jallcom.2017.07.005
  • 出版年:   2017

▎ 摘  要

Inspired by hierarchical structures of natural species, we developed a facile and inexpensive approach to synthesize a novel hierarchical modified porous carbon/graphene (MPC/RGO) composite material. The porous carbon was obtained from sugarcane bagasse and later combined with reduced graphene oxide by using a hydrothermal method to produce the MPC/RGO. The obtained MPC/RGO composite was characterized by X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM) and transmission electron microscopy (TEM). As an anode for lithium-ion battery, it delivers a high reversible discharging capacity of 617.3 mAh g(-1) after 600 cycles at a current density of 200 mA g(-1), which is significantly higher than 272.5 mAh g(-1) of the mechanical mixture of the modified porous carbon (MPC) and RGO at the same testing condition. This impressive electrochemical performance showed by the MPC/RGO composite is attributed to the chemical bonds formed between the reduced graphene oxide sheets and the hierarchical porous carbon. This simple synthesis approach and the high performance of the product is a dream combination in the development of novel and smart materials. (C) 2017 Elsevier B.V. All rights reserved.