• 文献标题:   A general potentiodynamic approach for red phosphorus and sulfur nanodot incorporation on reduced graphene oxide sheets: metal-free and binder-free electrodes for supercapacitor and hydrogen evolution activities
  • 文献类型:   Article
  • 作  者:   KHALID M, VARELA H
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY A
  • ISSN:   2050-7488 EI 2050-7496
  • 通讯作者地址:   Univ Sao Paulo
  • 被引频次:   6
  • DOI:   10.1039/c7ta11342k
  • 出版年:   2018

▎ 摘  要

A general potentiodynamic strategy, for the first time, was proposed to incorporate red phosphorus (P) and sulfur (S) nanodots on reduced graphene oxide sheets (rGO) on a carbon fabric support. Uniformly embedded nanodots on rGO sheets were visualized using transmission electron microscopy. The as-prepared metal-free and binder-free electrodes can serve for both supercapacitors and the hydrogen evolution reaction. In particular, P nanodot incorporated rGO demonstrates a high specific capacitance of 334.2 F g(-1), of which 99.2% is retained after 10 000 repeated charge/discharge cycles. Furthermore, this material delivers a current density of 10 mA cm(-2) at an overpotential of -0.44 V versus RHE for the hydrogen evolution reaction in acidic medium.