• 文献标题:   Layer-resolved Raman imaging and analysis of parasitic ad-layers in transferred graphene
  • 文献类型:   Article
  • 作  者:   DOBROWOLSKI A, JAGIELLO J, CIUK T, PIETAK K, MOZDZYNSKA EB
  • 作者关键词:   graphene, transfer, raman spectroscopy, adlayer, structural analysi, topographic imaging
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.1016/j.apsusc.2022.155054 EA OCT 2022
  • 出版年:   2023

▎ 摘  要

In this report, we demonstrate an applied protocol for layer-resolved Raman imaging and analysis of undesirable ad-layers found in Chemical Vapor Deposition graphene grown on copper foil and transferred onto an oxidized silicon substrate. The method assumes that the intensity of the silicon-related Raman-active mode at 520 cm-1 is attenuated by 2.3 % each time the light passes through a single graphene layer. Upon normalization with respect to a reference graphene-free area, the 520 cm-1 mode relative intensity r-ISi measured in a back -scatter mode follows a univalent function of the number of the graphene layers N. Since N is treated as a continuous argument, it can be ascribed a fractional value and considered statistically. Importantly, the r-ISi offers higher layer differentiation capability and unambiguity than non-functional indicators, including the 2D band width or the 2D-to-G band intensity ratio, thus providing unequivocal evaluation.