▎ 摘　　要

Functional two-dimensional (2D) graphene-like carbon has the potential to be a good electromagnetic wave absorbing material due to its good electronic properties, but the preparation of 2D carbon via metal-organic frameworks (MOFs) derivation method is still a bottleneck. Herein, we fabricated ultrathin nitrogen-doped graphene-like carbon nanomesh (N-GN) via thermal exfoliation of 2D MOF (Zn-ZIF-L) directly. The species of the chloride salt that exfoliated Zn-ZIF-L have an effect on the nitrogen content, graphitization degree, pore size and specific surface area of N-GN. The Zn-ZIF-L derived N-GN exfoliated by KCl and LiCl simultaneously has the optimum reflection loss of-54 dB only with the thickness of 2.1 mm and the filler loading of 3 wt%. The excellent electromagnetic wave absorbing property is attributed to its favorable structure, micro-meso-macropores, N heteroatoms, abundant heterogeneous graphene-like carbon nanomesh interfaces and defects. Our simple and low-cost preparation process facilitates the large-scale production and application for electro-magnetic wave absorbing material of functionalized graphene-like carbon.