• 文献标题:   Graphene oxide wrapped CH3NH3PbBr3 perovskite quantum dots hybrid for photoelectrochemical CO2 reduction in organic solvents
  • 文献类型:   Article
  • 作  者:   WANG QL, TAO LM, JIANG XX, WANG MK, SHEN Y
  • 作者关键词:   graphene oxide, perovskite quantum dot, photoelectrochemical co2 reduction
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Huazhong Univ Sci Technol
  • 被引频次:   28
  • DOI:   10.1016/j.apsusc.2018.09.215
  • 出版年:   2019

▎ 摘  要

Lead halide perovskite have primarily considered as photovoltaic materials for luminescent materials and optoelectronic devices. However, lead halide perovskite is assumed to be unsuitable for photoelectrochemical conversion due to the instability in humid environment or polar solvents. Here, we report graphene oxide (GO) wrapped organic-inorganic lead halide perovskite quantum dots (GO/CH3NH3PbBr3 hybrid) for photoelectrochemical conversion CO2 into solar fuels in nonaqueous media. Graphene oxide can protect CH3NH3PbBr3 QDs from erosion by organic solvent, and also serve as electron transport medium to separate photoinduced electrons and holes. Therefore, a photocurrent increase by ca. 200% can be obtained in the GO/CH3NH3PbBr3 hybrid due to improved electron extraction and transport. The GO/CH3NH3PbBr3 electrode exhibits an effective CO2 reduction capacity to CO, yielding 1.05 mu mol cm(-2) h(-1).