• 文献标题:   Phase change microcapsules with graphene nanoplates embedded polyurea shell for enhanced thermal conductivity
  • 文献类型:   Article
  • 作  者:   CHEN YB, YANG GW, CHEN LY, WANG BJ, FENG XL, MAO ZP, SUI XF, XU H
  • 作者关键词:   phase change material, thermal conductivity, carbon material, regenerated chitin, pickering emulsion, energy storage conversion
  • 出版物名称:   MATERIALS LETTERS
  • ISSN:   0167-577X EI 1873-4979
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1016/j.matlet.2022.133223 EA SEP 2022
  • 出版年:   2023

▎ 摘  要

Microencapsulated phase change materials with graphene nanoplates (GNPs) embedded polyurea shell and n-docosane (C-22) as core material were fabricated via Pickering emulsion polymerization. GNPs was used in combination with regenerated nanochitin as Pickering emulsifiers for enhanced stability due to mutual hydrophobic and electrostatic interactions. The microcapsules with 10 wt% GNPs (GNPs10/PU@C-22) exhibited melting enthalpy as high as 185.5 J/g and thermal conductivity as high as 0.65 W/m.K. GNPs10/PU@C-22 was also used to prepare composite films that showed great potential in thermal management of mobile phone devices.