• 文献标题:   Bright Electroluminescence from Single Graphene Nanoribbon Junctions
  • 文献类型:   Article
  • 作  者:   CHONG MC, AFSHARIMANI N, SCHEURER F, CARDOSO C, FERRETTI A, PREZZI D, SCHULL G
  • 作者关键词:   graphene nanoribbon, electroluminescence, singlemolecule junction, scanning tunneling microscopy induced light emission, density functional theory, gwbse
  • 出版物名称:   NANO LETTERS
  • ISSN:   1530-6984 EI 1530-6992
  • 通讯作者地址:   Univ Strasbourg
  • 被引频次:   17
  • DOI:   10.1021/acs.nanolett.7b03797
  • 出版年:   2018

▎ 摘  要

Thanks to their highly tunable band gaps, graphene nanoribbons (GNRs) with atomically precise edges are emerging as mechanically and chemically robust candidates for nanoscale light emitting devices of modulable emission color. While their optical properties have been addressed theoretically in depth, only few experimental studies exist, limited to ensemble measurements and without any attempt to integrate them in an electronic-like circuit. Here we report on the electroluminescence of individual GNRs suspended between the tip of a scanning tunneling microscope (STM) and a Au(111) substrate, constituting thus a realistic optoelectronic circuit. Emission spectra of such GNR junctions reveal a bright and narrow band emission of red light, whose energy can be tuned with the bias voltage applied to the junction, but always lying below the gap of infinite GNRs. Comparison with ab initio calculations indicates that the emission involves electronic states localized at the GNR termini. Our results shed light on unpredicted optical transitions in GNRs and provide a promising route for the realization of bright, robust, and controllable graphene-based light-emitting devices.