• 文献标题:   Synthesis of graphene-like porous carbon from biomass for electrochemical energy storage applications
  • 文献类型:   Article
  • 作  者:   YELEUOV M, DAULBAYEV C, TAURBEKOV A, ABDISATTAR A, EBRAHIM R, KUMEKOV S, PRIKHODKO N, LESBAYEV B, BATYRZHAN K
  • 作者关键词:   graphenelike porous carbon, fewlayer graphene, walnut shell, biowaste derived, electrochemical double layer capacitor
  • 出版物名称:   DIAMOND RELATED MATERIALS
  • ISSN:   0925-9635 EI 1879-0062
  • 通讯作者地址:  
  • 被引频次:   14
  • DOI:   10.1016/j.diamond.2021.108560 EA AUG 2021
  • 出版年:   2021

▎ 摘  要

Graphene-like porous carbon (GLC) was synthesized from walnut shell (WSh) by carbonization and thermochemical activation process. The obtained samples of graphene-like porous carbon based on walnut shell (GLCWSh) were characterized by physicochemical analysis in order to optimize the synthesis process. The optimum condition of GLC-WSh synthesis was determined to meet the basic requirements for various applications such as an active material for supercapacitors, lithium-ion battery, as energy-intensive additives in order to increase the efficiency of high-energy rocket fuels, and as a membrane for desalination of seawater. The Raman spectra confirmed the presence of few-layer graphene in GLC-WSh with on average number of 5-7 graphene layers. The specific surface area (SSA) was determined using nitrogen adsorption/desorption analysis. The SSA is 2800 m(2) g (-1) according to Brunauer-Emmett-Teller method. The mass yield of GLC-WSh from the initial mass of the WSh was 21%. The synthesized GLC-WSh powder was applied as an active material for an electrochemical double layer capacitor. Electrochemical characterization showed a high specific capacitance value of 263 F/ g and columbic efficiency of 99.4% at a gravimetric current density of 1000 mA/ g.