• 文献标题:   Epitaxial graphene/silicon carbide intercalation: a minireview on graphene modulation and unique 2D materials
  • 文献类型:   Review
  • 作  者:   BRIGGS N, GEBEYEHU ZM, VERA A, ZHAO T, WANG K, DURAN AD, BERSCH B, BOWEN T, KNAPPENBERGER KL, ROBINSON JA
  • 作者关键词:  
  • 出版物名称:   NANOSCALE
  • ISSN:   2040-3364 EI 2040-3372
  • 通讯作者地址:   Penn State Univ
  • 被引频次:   8
  • DOI:   10.1039/c9nr03721g
  • 出版年:   2019

▎ 摘  要

Intercalation of atomic species through epitaxial graphene on silicon carbide began only a few years following its initial report in 2004. The impact of intercalation on the electronic properties of the graphene is well known; however, the intercalant itself can also exhibit intriguing properties not found in nature. This realization has inspired new interest in epitaxial graphene/silicon carbide (EG/SiC) intercalation, where the scope of the technique extends beyond modulation of graphene properties to the creation of new 2D forms of 3D materials. The mission of this minireview is to provide a concise introduction to EG/SiC intercalation and to demonstrate a simplified approach to EG/SiC intercalation. We summarize the primary techniques used to achieve and characterize EG/SiC intercalation, and show that thermal evaporation-based methods can effectively substitute for more complex synthesis techniques, enabling large-scale intercalation of non-refractory metals and compounds including two-dimensional silver (2D-Ag) and gallium nitride (2D-GaNx).