• 文献标题:   Preparation and Adsorption Performance of Efficient Adsorbent for Heavy Metal Copper(II) Using Graphene-Oxide-Based Composites
  • 文献类型:   Article
  • 作  者:   LIU HD, GUO JY, ZHOU YH, QIAN J
  • 作者关键词:   graphene, adsorption, cu2+, polyethylene imine, carboxymethyl cellulose
  • 出版物名称:   CHEMISTRYSELECT
  • ISSN:   2365-6549
  • 通讯作者地址:   Wuhan Univ
  • 被引频次:   0
  • DOI:   10.1002/slct.202003189
  • 出版年:   2020

▎ 摘  要

Graphene oxide/polyethylene imine (GO/PEI) and graphene oxide/polyethylene imine/carboxymethyl cellulose (GO/PEI/CMC), these two kinds of composite adsorbent materials for heavy metal Cu(2+)were prepared by cross-linking and graft copolymerization, and the GO was obtained by an improved method of Hummers in this work. The adsorption properties of GO, GO/PEI and GO/PEI/CMC on Cu(2+)were compared and analyzed with the initial pH value of solution, adsorption time, initial concentration of Cu(2+)and adsorbent dosage as the indicators. The results showed that the optimal adsorption pH of GO/PEI and GO/PEI/CMC for Cu(2+)were 5.0 similar to 5.5; both GO/PEI and GO/PEI/CMC reached adsorption equilibrium in 195 min; when the adsorption is saturated, compared with the maximum adsorption capacity of GO (112.91 mg.g(-1)), the maximum adsorption capacity of GO/PEI and GO/PEI/CMC for Cu(2+)reaches 294.41 mg g(-1)and 302.04 mg g(-1), respectively. Moreover, GO/PEI/CMC is more convenient for solid-liquid separation after adsorption, which is a kind of adsorption material with more practical application potential.