• 文献标题:   Stretch-Induced Stiffness Enhancement of Graphene Grown by Chemical Vapor Deposition
  • 文献类型:   Article
  • 作  者:   LIN QY, JING G, ZHOU YB, WANG YF, MENG J, BIE YQ, YU DP, LIAO ZM
  • 作者关键词:   afm, nanoindentation, zerodisplacement point, wrinkle, young s modulu
  • 出版物名称:   ACS NANO
  • ISSN:   1936-0851 EI 1936-086X
  • 通讯作者地址:   NW Univ Xian
  • 被引频次:   39
  • DOI:   10.1021/nn3053999
  • 出版年:   2013

▎ 摘  要

The mechanical properties of ultrathin membranes have attracted considerable attention recently. Nanoindentation based on atomic force microscopy is commonly employed to study mechanical properties. We find that the data processing procedures in previous studies are nice approximations, but it is difficult for them to illustrate the mechanical properties precisely. Accordingly, we develop a revised numerical method to describe the force curve properly, by which the intrinsic mechanical properties of these membranes can be acquired. Combining the nanoindentation measurements with the revised numerical method, we demonstrate that loading-unloading cycles under large load can lead to a pronounced improvement in stiffness of graphene grown by chemical vapor deposition (CVD). The Young's moduli of the stretched CVD graphene membranes can be improved to similar to 1 TPa, closing to the value of the pristine graphene. Our findings demonstrate a possible way to recover the exceptional elastic properties of CVD graphene from the softened stiffness caused by wrinkles.