• 文献标题:   Amperometric Determination of Sulfide by Glassy Carbon Electrode Modified with Hemin Functionalized Reduced Graphene Oxide
  • 文献类型:   Article, Proceedings Paper
  • 作  者:   CAO XD, GAO JN, YE YW, WANG PF, DING S, YE YK, SUN HJ
  • 作者关键词:   sulfide, hemin functionalized reduced graphene oxide, modified glassy carbon electrode, amperometric determination
  • 出版物名称:   ELECTROANALYSIS
  • ISSN:   1040-0397 EI 1521-4109
  • 通讯作者地址:   Hefei Univ Technol
  • 被引频次:   7
  • DOI:   10.1002/elan.201500508
  • 出版年:   2016

▎ 摘  要

This work describes a new approach for rapid detection of sulfide using a glassy carbon electrode (GCE) modified with hemin functionalized reduced graphene oxide (hemin-rGO). The modified GCE was applied to the selective amperometric detection of sulfide at a working potential of 0.05V (vs. Ag/AgCl) at pH7.5, which gave a linear range of 0.002-0.212mM, a sensitivity of 246.5 mu AmM(-1)cm(-2), and a detection limit of 1.3 mu M. The proposed method was applied in determination of sulfide-spiked water, and the method was verified with recovery percentage of standard samples with an acceptable satisfaction.