• 文献标题:   Reduced graphene oxide-supported Cu nanoparticles for the selective oxidation of benzyl alcohol to aldehyde with molecular oxygen
  • 文献类型:   Article
  • 作  者:   FENG X, LV PP, SUN W, HAN XY, GAO LF, ZHENG GX
  • 作者关键词:   graphene, copper nanoparticle, oxidation, benzyl alcohol, benzaldehyde
  • 出版物名称:   CATALYSIS COMMUNICATIONS
  • ISSN:   1566-7367 EI 1873-3905
  • 通讯作者地址:   Univ Jinan
  • 被引频次:   12
  • DOI:   10.1016/j.catcom.2017.05.013
  • 出版年:   2017

▎ 摘  要

Copper nanoparticles supported on reduced graphene oxide (Cu@rGO) were prepared at room temperature via one-step reduction of graphene oxide and copper ions. Analyses by means of X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS) confirmed that copper was successfully decorated over the rGO sheets. The Cu@rGO nanocomposite can be used as an efficient heterogeneous catalyst in selective oxidation of benzyl alcohol to benzaldehyde with 97% conversion and 98% selectivity. The synergistic effect between copper nanoparticles and graphene results in a highly active and stable catalyst for several cycles of use.