• 文献标题:   Graphene Oxide-Doped Polymer Inclusion Membrane for Remediation of Pharmaceutical Contaminant of Emerging Concerns: Ibuprofen
  • 文献类型:   Article
  • 作  者:   AHMAD AL, EBENEZER OI, SHOPARWE NF, ISMAIL S
  • 作者关键词:   ibuprofen, contaminants of emerging concern, polymer inclusion membrane, graphene oxide, chemical stability, wastewater, remediation
  • 出版物名称:   MEMBRANES
  • ISSN:  
  • 通讯作者地址:  
  • 被引频次:   8
  • DOI:   10.3390/membranes12010024
  • 出版年:   2022

▎ 摘  要

The application of polymer inclusion membranes (PIMs) for the aquatic remediation of several heavy metals, dyes, and nutrients has been extensively studied. However, its application in treating organic compounds such as Ibuprofen, an emerging pharmaceutical contaminant that poses potential environmental problems, has not been explored satisfactorily. Therefore, graphene oxide (GO) doped PIMs were fabricated, characterized, and applied to extract aqueous Ibuprofen at varied pH conditions. The doped PIMs were synthesized using a low concentration of Aliquat 336 as carrier and 0, 0.15, 0.45, and 0.75% GO as nanoparticles in polyvinyl chloride (PVC) base polymer without adding any plasticizer. The synthesized PIM was characterized by SEM, FTIR, physical, and chemical stability. The GO doped PIM was well plasticized and had an optimal Ibuprofen extraction efficiency of about 84% at pH of 10 and 0.75% GO concentration. Furthermore, the GO doped PIM's chemical stability indicates better stability in acidic solution than in the alkaline solution. This study demonstrates that the graphene oxide-doped PIM significantly enhanced the extraction of Ibuprofen at a low concentration. However, further research is required to improve its stability and efficiency for the remediation of the ubiquitous Ibuprofen in the aquatic environment.