• 文献标题:   Biodiesel production from wet microalgae by using graphene oxide as solid acid catalyst
  • 文献类型:   Article
  • 作  者:   CHENG J, QIU Y, HUANG R, YANG WJ, ZHOU JH, CEN KF
  • 作者关键词:   wet microalgae, biodiesel, graphene oxide, solid acid catalyst
  • 出版物名称:   BIORESOURCE TECHNOLOGY
  • ISSN:   0960-8524 EI 1873-2976
  • 通讯作者地址:   Zhejiang Univ
  • 被引频次:   29
  • DOI:   10.1016/j.biortech.2016.09.064
  • 出版年:   2016

▎ 摘  要

In order to produce biodiesel from lipids in wet microalgae with graphene oxide (GO) as solid acid catalyst, the effects on lipids conversion efficiencies of catalyst dosage, transesterification temperature, reaction time, methanol dosage and chloroform dosage were investigated. Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and elemental analysis revealed that GO contained 0.997 mmol SO3H groups per gram and high amounts of OH groups. Scanning electron microscopy showed that wet microalgae cells were adsorbed on hydrophilic GO surfaces covered with many OH groups. Lipids extracted by chloroform from microalgal cells were transformed into fatty acids methyl esters (FAMEs) through transesterification catalyzed by the acid centers (SO3H groups) in GO catalysts. The lipids conversion efficiency into FAMEs was 95.1% in microwave-assisted transesterification reactions of 5 wt.% GO catalyst at 90 degrees C for 40 min. (C) 2016 Elsevier Ltd. All rights reserved.