• 文献标题:   Explosion in the preparation of nanoparticles: monodisperse Ag inserted in 3D graphene sheets for the electrochemical detection of H2O2
  • 文献类型:   Article
  • 作  者:   BAO L, WU YX, LIU D, ZHAO CX, NING XH, DUAN QL, LI Y, ZHANG WY
  • 作者关键词:  
  • 出版物名称:   DALTON TRANSACTIONS
  • ISSN:   1477-9226 EI 1477-9234
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1039/d2dt02988j EA OCT 2022
  • 出版年:   2022

▎ 摘  要

In this work, the smashing effect of explosives innovatively led to the preparation of nanoparticles. The energetic material 3,5-dinitrobenzoic acid (DNBA) was introduced as a ligand to coordinate with silver ions and connect graphene sheets via electrostatic attraction in the sol-gel process. Owing to the thermolysis of DNBA, the pore-formation of graphene sheets, thermal reduction of Ag+ and achievement of monodisperse Ag nanoparticles were realized simultaneously. The morphology and composition of the nanocomposites were characterized by scanning electron microscopy, transmission electron microscopy, X-ray diffraction and X-ray photoelectron spectroscopy. Then, the nanocomposite was used to construct a hydrogen peroxide (H2O2) sensor, which displayed excellent catalytic performance over a wide linear concentration range of 4 x 10(-5) to 4 x 10(-3) mM with a corresponding sensitivity of 72 mu A mM(-1) cm(-2) and detection limit of 101.25 nM with a signal-to-noise ratio of 3.