• 文献标题:   Microwave assisted synthesis of porous carbon from graphene for enhanced adsorption of atrazine in aqueous solution
  • 文献类型:   Article
  • 作  者:   ZHU XZ, XU HL, XIE HW, TAN GC, GAO Y, XU N
  • 作者关键词:   atrazine adsorption, graphene, porous carbon, microwave, water purification
  • 出版物名称:   DESALINATION WATER TREATMENT
  • ISSN:   1944-3994 EI 1944-3986
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.5004/dwt.2021.26497
  • 出版年:   2021

▎ 摘  要

In order to improve the adsorption capacity of graphene oxide (GO), graphene-based porous carbon (GPC) was synthesized by a two-step activation method. Using chemical activation of microwave exfoliated GO, we obtained GPC with a high Brunauer-Emmett-Teller surface area of up to 1,598 m(2)/g and a large number of micropores. The GPC was firstly used as an adsorbent for the removal of atrazine in aqueous solution. The obtained adsorbent was characterized by scanning electron microscopy, BET, X-ray diffraction, Fourier transform infrared, and Raman spectroscopy. Experimental results indicated that GPC had excellent adsorption capacity (similar to 131.6 mg/g), which was much higher than that of GO synthesized by the Hummer' method. The adsorption process was more accurately represented by a pseudo-second-order model and Freundlich isotherm model for the adsorption of atrazine on GPC. The present adsorption studies of pesticides revealed the potential of GPC nanomaterial to be utilized as a promising adsorbent for organic pollutants.