• 文献标题:   One step synthesis cadmium sulphide/reduced graphene oxide sandwiched film modified electrode for simultaneous electrochemical determination of hydroquinone, catechol and resorcinol
  • 文献类型:   Article
  • 作  者:   HU SR, ZHANG WX, ZHENG JZ, SHI JG, LIN ZQ, ZHONG L, CAI GX, WEI C, ZHANG HQ, HAO AY
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Shandong Univ
  • 被引频次:   23
  • DOI:   10.1039/c4ra16268d
  • 出版年:   2015

▎ 摘  要

In this work, a novel sandwiched film of cadmium sulphide/reduced graphene oxide (CdS/r-GO) was synthesized via one step hydro-thermal reaction and electrodes modified with this composite were successfully used to simultaneously determine hydroquinone (HQ), catechol (CC) and resorcinol (RC). Additionally, some kinetic parameters, such as the charge transfer coefficient (alpha) and the electron transfer rate constant (k(s)) were calculated. Differential pulse voltammetry (DPV) was used for the simultaneous determination of HQ, CC and RC in their ternary mixture. The calibration curves of HQ, CC and RC were obtained in the ranges of 0.2 to 2300 mu M, 0.5 to 1350 mu M and 1.0 to 500 mu M, respectively. The detection limits for HQ, CC and RC were 0.054 mu M, 0.09 mu M and 0.23 mu M, respectively (S/N = 3). The modified electrode was then used to analyse tap water, well water and river water and the results show its significance for practical applications in the aquatic environment.