• 文献标题:   Significance of N-moieties in regulating the electrochemical properties of nano-porous graphene: Toward highly capacitive energy storage devices
  • 文献类型:   Article
  • 作  者:   KHAN F, KIM JH
  • 作者关键词:   porous graphene, nitrogen moietie, nitrogen doping, electrochemical propertie
  • 出版物名称:   JOURNAL OF INDUSTRIAL ENGINEERING CHEMISTRY
  • ISSN:   1226-086X EI 1876-794X
  • 通讯作者地址:   DGIST
  • 被引频次:   1
  • DOI:   10.1016/j.jiec.2018.07.037
  • 出版年:   2018

▎ 摘  要

The effects of N doping concentration and dopant moieties on the electrochemical properties of nanoporous graphene and their dependence on annealing temperature are investigated. Four types of N moieties - amide, amine, graphitic-N, and oxidized-N - are obtained, which transformed into pyridinic-N and pyrrolic-N upon annealing. The diffusion coefficient (0') of the ions in the electrode is the maximum at 400 degrees C because of a high level of N doping, whereas the second highest D' value is obtained at 700 degrees C owing to a high level of reduction and N doping. The highest specific capacitance is obtained for the sample annealed at 400 degrees C. (C) 2018 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.