• 文献标题:   Synthesis, characterization, and electrochemical properties of the modified graphene oxide with 4,4 '-methylenedianiline
  • 文献类型:   Article
  • 作  者:   NIKKHAH S, TAHERMANSOURI H, CHEKIN F
  • 作者关键词:   carbon material, graphene oxide, functional, electrocatalysi
  • 出版物名称:   MATERIALS LETTERS
  • ISSN:   0167-577X EI 1873-4979
  • 通讯作者地址:   Islamic Azad Univ
  • 被引频次:   1
  • DOI:   10.1016/j.matlet.2017.10.037
  • 出版年:   2018

▎ 摘  要

Graphene oxide (GO) was modified by 4,4 '-methylenedianiline to form a nanocomposite material (GO-amine). Materials were characterized by Fourier transform infrared spectroscopy, thermogravimetric analysis, derivative thermogravimetric and field emission scanning electron microscopy. The electrochemical behavior of modified carbon paste electrode (CPE) with GO-amine (GO-amine/CPE) was studied by electrochemical methods. The results showed which GO-amine/CPE catalyzes oxygen evolution reaction in alkaline media with an onset potential of 0.4 V (vs. Ag|AgCl|KCl3M), showing a synergistic effect between GO and amine nanocomposite. The high electrochemical stability confirmed the improved electrocatalytic performance of GO-amine. This study affords us a GO-amine based electrocatalyst with high performance and strong durability under alkaline conditions, which can be applied to energy conversion and storage. (C) 2017 Elsevier B.V. All rights reserved.