• 文献标题:   Limits to the Optical Response of Graphene and Two-Dimensional Materials
  • 文献类型:   Article
  • 作  者:   MILLER OD, ILIC O, CHRISTENSEN T, REID MTH, ATWATER HA, JOANNOPOULOS JD, SOLJACIC M, JOHNSON SG
  • 作者关键词:   2d material, graphene, upper bound, nearfield optic, nonlocality
  • 出版物名称:   NANO LETTERS
  • ISSN:   1530-6984 EI 1530-6992
  • 通讯作者地址:   Yale Univ
  • 被引频次:   12
  • DOI:   10.1021/acs.nanolett.7b02007
  • 出版年:   2017

▎ 摘  要

Two-dimensional (2D) materials provide a platform for strong light matter interactions, creating wide-ranging design opportunities via new-material discoveries and new methods for geometrical structuring. We derive general upper bounds to the strength of such light matter interactions, given only the optical conductivity of the material, including spatial nonlocality, and otherwise independent of shape and configuration. Our material figure-of-merit shows that highly doped graphene is an optimal material at infrared frequencies, whereas single-atomic-layer silver is optimal in the visible. For quantities ranging from absorption and scattering to near-field spontaneous-emission enhancements and radiative heat transfer, we consider canonical geometrical structures and show that in certain cases the bounds can be approached, while in others there may be significant opportunity for design improvement. The bounds can encourage systematic improvements in the design of ultrathin broadband absorbers, 2D antennas, and near-field energy harvesters.