• 文献标题:   Durable graphene-coated bipolar plates for polymer electrolyte fuel cells
  • 文献类型:   Article
  • 作  者:   LEE YH, NOH S, LEE JH, CHUN SH, CHA SW, CHANG I
  • 作者关键词:   graphene, bipolar plate, polymer electrolyte fuel cell, oxidation, chemical vapor deposition
  • 出版物名称:   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
  • ISSN:   0360-3199 EI 1879-3487
  • 通讯作者地址:   Dept Phys
  • 被引频次:   5
  • DOI:   10.1016/j.ijhydene.2017.09.053
  • 出版年:   2017

▎ 摘  要

In this paper, we investigate the role of a graphene layer for polymer electrolyte fuel cells (PEFCs) which require an ultrathin protective layer for copper bipolar plates. The graphene layer was deposited by chemical vapor deposition using CH4 at 830 degrees C. We examined the deposited graphene layer to characterize microstructural properties using a Raman spectroscopy microscope and a secondary electron microscope. During the electrochemical tests, the current-voltage-power (I-V-P) performance of the single cell using the copper bipolar plate with the graphene layer was highly stable for 5 h, while the I-V-P performance of the single cell using the pure copper bipolar plate (without the graphene layer) was much lower. We conclude that the graphene layer acts as a very thin passivation layer on the copper bipolar plate of a PEFC. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.