• 文献标题:   Green Synthesis of Free Standing Cellulose/Graphene Oxide/Polyaniline Aerogel Electrode for High-Performance Flexible All-Solid-State Supercapacitors
  • 文献类型:   Article
  • 作  者:   LI YQ, XIA ZB, GONG Q, LIU XH, YANG Y, CHEN C, QIAN CH
  • 作者关键词:   cellulose, graphene oxide, polyaniline, aerogel electrode, supercapacitor
  • 出版物名称:   NANOMATERIALS
  • ISSN:  
  • 通讯作者地址:   Nanjing Forestry Univ
  • 被引频次:   0
  • DOI:   10.3390/nano10081546
  • 出版年:   2020

▎ 摘  要

The cellulose/graphene oxide (GO) networks as the scaffold of free-standing aerogel electrodes are developed by using lithium bromide aqueous solution, as the solvent, to ensure the complete dissolution of cotton linter pulp and well dispersion/reduction of GO nanosheets. Polyaniline (PANI) nanoclusters are then coated onto cellulose/GO networks via in-situ polymerization of aniline monomers. By optimized weight ratio of GO and PANI, the ternary cellulose/GO(3.5)/PANI aerogel film exhibits well-defined three-dimensional porous structures and high conductivity of 1.15 S/cm, which contributes to its high areal specific capacitance of 1218 mF/cm(2)at the current density of 1.0 mA/cm(2). Utilizing this cellulose/GO(3.5)/PANI aerogel film as electrodes in a symmetric configuration supercapacitor can result in an outstanding energy density as high as 258.2 mu Wh/cm(2)at a power density of 1201.4 mu W/cm(2). Moreover, the device can maintain nearly constant capacitance under different bending deformations, suggesting its promising applications in flexible electronics.