• 文献标题:   Graphene: a self-reducing template for synthesis of graphene-nanoparticles hybrids
  • 文献类型:   Article
  • 作  者:   DEVI MM, SAHU SR, MUKHERJEE P, SEN P, BISWAS K
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Indian Inst Technol
  • 被引频次:   8
  • DOI:   10.1039/c5ra10593e
  • 出版年:   2015

▎ 摘  要

The integration of graphene with certain metallic nanoparticles, such as Au, Ag, Pt, Pd, Cu, etc., to produce a new generation of hybrid materials is a field of intense research nowadays. Graphene, being a single atom thick layer sheet of hexagonally arranged sp(2) carbon atoms, has a prodigious number of free electrons, which can be used to reduce metallic ions to produce a hybrid material consisting of metal nanoparticles on the 2D fabric of graphene. Efforts were made to explore such property of the virgin graphene by careful in situ study using UV-visible (UV-vis) spectroscopy and transmission electron microscopy (TEM). The results indicate that it is possible to use surface potential of graphene to reduce Au3+, Ag+, Pt2+, Pd2+ and Cu2+ ions to prepare graphene-metal nanoparticle hybrids. The extensive TEM studies substantiate the finding of the formation of graphene decorated with metal nanoparticles.