• 文献标题:   Influence of interface hydration on sliding of graphene and molybdenum-disulfide single-layers
  • 文献类型:   Article
  • 作  者:   LIN H, RAUF A, SEVERIN N, SOKOLOV IM, RABE JP
  • 作者关键词:   graphene, mos2, friction, interface wetting, raman, photoluminescence
  • 出版物名称:   JOURNAL OF COLLOID INTERFACE SCIENCE
  • ISSN:   0021-9797 EI 1095-7103
  • 通讯作者地址:   Humboldt Univ
  • 被引频次:   3
  • DOI:   10.1016/j.jcis.2018.12.089
  • 出版年:   2019

▎ 摘  要

Humidity influences friction in layered materials in peculiar ways. For example, while water improves the lubricating properties of graphite, it deteriorates those of molybdenum disulfide (MoS2). The reasons remain debated, not the least due to the difficulty in experimentally comparing dry and hydrated interface frictions. Here we show that the hydration of interfaces between a mica substrate and single-layers of graphene and MoS2 with a molecularly thin water layer affects strain transfer from the substrate to the 2D materials. For this, we strain the substrate and detect strain in graphene and MoS2 by changes in Raman and photoluminescence spectra, respectively. Strain relaxation in graphene changes from stick slip in dry contact, to viscous when hydrated. In contrast, there is no viscous relaxation in MoS2 regardless of hydration. Our work provides a novel approach for better understanding the impact of hydration on friction in layered materials. (C) 2018 Elsevier Inc. All rights reserved.