• 文献标题:   Electrocatalytic Activity of Reduced Graphene Oxide Supported Cobalt Cinnamate for Oxygen Evolution Reaction
  • 文献类型:   Article
  • 作  者:   LEE MJ, KIM J, KANG J, SHIN H, DO J, KWON SJ
  • 作者关键词:   oxygen evolution reaction, electrocatalyst, porous coordination polymer, metalorganic framework, graphene oxide composite
  • 出版物名称:   ENERGIES
  • ISSN:  
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.3390/en14165020
  • 出版年:   2021

▎ 摘  要

The stability of porous coordination polymers during an electrochemical reaction could be improved by introducing supporter materials. An (IO0)-O-3-type inorganic hybrid electrocatalyst, cobalt cinnamate, supported on reduced graphene oxide (rGO) was successfully prepared for an oxygen evolution reaction. The electrocatalytic activity and stability of cobalt cinnamate(catalyst)/rGO composite were significantly improved due to the strong interaction between catalyst and supporter, which led to enhanced anchoring stability and electrical conductivity. The catalyst/rGO composite shows similar to 30 mV reduction in overpotential and improvement in durability from >= 35% to >= 70% after a reaction time of 12 h, compared to the catalyst alone.