• 文献标题:   Time evolution of the growth of single graphene crystals and high resolution isotope labeling
  • 文献类型:   Article
  • 作  者:   WHITEWAY E, YANG WN, YU V, HILKE M
  • 作者关键词:  
  • 出版物名称:   CARBON
  • ISSN:   0008-6223 EI 1873-3891
  • 通讯作者地址:   McGill Univ
  • 被引频次:   3
  • DOI:   10.1016/j.carbon.2016.09.034
  • 出版年:   2017

▎ 摘  要

We developed a method of precise isotope labeling to visualize the continuous growth of graphene by chemical vapour deposition (CVD). This method allows us to observe, as a function of time, the growth of graphene monocrystals at a resolution of a few seconds. This technique is used to extract the anisotropic growth rates, as well as investigate the formation of dendrites, and the dependence of growth rate on adsorption area of methane on copper. This technique also gives precise start times for individual graphene nucleation sites. We obtain a physical picture of the growth dynamics of graphene and its dependence on various parameters. Finally, our method is relevant to other CVD grown materials. (C) 2016 Elsevier Ltd. All rights reserved.