• 文献标题:   Effect of reduced graphene oxide on the structural, optical, adsorption and photocatalytic properties of iron oxide nanoparticles
  • 文献类型:   Article
  • 作  者:   SURESH R, UDAYABHASKAR R, SANDOVAL C, RAMIREZ E, MANGALARAJA RV, MANSILLA HD, CONTRERAS D, YANEZ J
  • 作者关键词:  
  • 出版物名称:   NEW JOURNAL OF CHEMISTRY
  • ISSN:   1144-0546 EI 1369-9261
  • 通讯作者地址:   Univ Concepcion
  • 被引频次:   4
  • DOI:   10.1039/c8nj00321a
  • 出版年:   2018

▎ 摘  要

Functionalized Fe2O3 nanoparticles with low concentrations (1, 3 and 5 wt%) of reduced graphene oxide (rGO) were prepared by the thermal decomposition method. In accordance with X-ray diffraction (XRD), Fourier transform infrared (FTIR), UV-visible, and photoluminescence (PL) spectroscopies, a phase change from hematite (-Fe2O3) to maghemite (-Fe2O3) was observed upon addition of rGO. The TEM investigation revealed that rGO led to the distortion of the Fe2O3 nanocuboid rods into spherical nanoparticles. The functionalized rGO acts as an electron accepter and led to the quenching of the luminescence behavior of Fe2O3. The functionalization of Fe2O3 with 5% rGO significantly increases its surface area and thus enhanced adsorption of acid blue 113 (AB(113)) from water was achieved. The adsorption studies revealed that 5%rGO/Fe2O3 (200 mg) adsorbed 89.6% of AB(113) (100 mg L-1) within 440 min. In comparison with pure Fe2O3, the 5%rGO/Fe2O3 also exhibits excellent photocatalytic activity in the degradation of AB(113) under visible light irradiation.