• 文献标题:   CVD Assisted Hydrophobic Graphene Quantum Dots: Fluorescence Sensor for Aromatic Amino Acids
  • 文献类型:   Article
  • 作  者:   DEKA MJ, CHOWDHURY D
  • 作者关键词:   amino acid, chemical vapor deposition, fluorescence, graphene quantum dot, sensor
  • 出版物名称:   CHEMISTRYSELECT
  • ISSN:   2365-6549
  • 通讯作者地址:   Inst Adv Study Sci Technol
  • 被引频次:   6
  • DOI:   10.1002/slct.201601737
  • 出版年:   2017

▎ 摘  要

In this paper, an hydrophobic graphene quantum dots(h-GQDs) based PL sensor was demonstrated which can distinguish between aromatic and non-aromatic amino acids. The h-GQDSs prepared using Chemical Vapour Deposition method from acetylene gas and hydrogen gas was used as cocatalyst. The characterization of h-GQDs was carried out by UV-Visible absorption spectrophotometer, Dynamic Light Scattering, Scanning Electron Microscopy, Fourier Transform Infrared Spectrophotometer, Raman spectroscopy. These CVD assisted h-GQDs form stable dispersion in organic solvents and are hydrophobic in nature. It was observed that photoluminescence (PL) intensity of h-GQDs systems in the presence of aromatic amino acids is enhanced due to electron transfer from aromatic amino acids to h-GQDs whereas with non-aromatic amino acids PL intensity is quenched. Hence h-GQDs systems can selectively distinguish between aromatic and non-aromatic amino acid. The mechanistic insight is also discussed in the paper. Besides fluorescence sensors for aromatic amino acids, the h-GQDs system can also be used as a fluorescence hydrophobic coating material as when coated on glass substrate it shows very high contact angle (107 degrees).