• 文献标题:   A CdTe/CdS quantum dots amplified graphene quantum dots anodic electrochemiluminescence platform and the application for ascorbic acid detection in fruits
  • 文献类型:   Article
  • 作  者:   CHEN HJ, LI W, ZHAO P, NIE Z, YAO SZ
  • 作者关键词:   nitrogen functional graphene quantum dot, cdte/cds quantum dot, anodic electrochemiluminescence, ascorbic acid, fruit
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Hunan Univ
  • 被引频次:   26
  • DOI:   10.1016/j.electacta.2015.08.015
  • 出版年:   2015

▎ 摘  要

Herein, a CdTe/CdS QDs (with a CdTe core and a CdS shell) amplified electrogenerated chemiluminescence (ECL) of nitrogen functional graphene quantum dots (NGQDs) platform is reported. The utilization of CdTe/CdS QDs could facilitate the production of NGQDs radical, and then, a high yield of NGQDs* was formed due to the interaction of NGQDs radical with O-2(center dot), leading to an similar to 21-fold ECL enhancement. This ECL enhancing system does not require the addition of coreactant and modification of electrode which is carried out in homogeneous solution. Benefiting from the remarkable ECL enhancement effect, a feasible and sensitive ECL sensor was constructed for ascorbic acid (AA) quantification. The proposed method features a detection limit of 70 nM with a linear calibration range from 100 nM to 100 mu M, and exhibits good stability, practicability, and acceptable fabrication reproducibility, showing promising application in real-sample. (C) 2015 Elsevier Ltd. All rights reserved.