• 文献标题:   Dependence of reduction degree on electromagnetic absorption of graphene nanoribbon unzipped from carbon nanotube
  • 文献类型:   Article
  • 作  者:   DING YJ, ZHU JQ, WANG SS, YANG ML, YANG S, YANG L, ZHAO X, XU F, WANG ZJ, LI YB
  • 作者关键词:   graphene oxide nanoribbon, unzipping, controllable reduction, electromagnetic wave absorption
  • 出版物名称:   JOURNAL OF COLLOID INTERFACE SCIENCE
  • ISSN:   0021-9797 EI 1095-7103
  • 通讯作者地址:   Harbin Inst Technol
  • 被引频次:   10
  • DOI:   10.1016/j.jcis.2019.05.033
  • 出版年:   2019

▎ 摘  要

Carbon materials are very promising for electromagnetic wave absorption application due to their light weight and low cost, where the reflection loss is used to evaluate the absorption efficiency. However, the reflection loss of carbon materials (carbon foam, graphene, and carbon nanotube) without loading magnetic particles is not as high as expected. Here, we propose to unzip carbon nanotubes into graphene oxide nanoribbons (GONRs), followed by controllable reduction treatment using hydrazine hydrate, and the reduced GONRs were finalized (called as r-GONRs). The r-GONRs exhibit obvious dielectric relaxation behaviors compared to GONRs, and the dielectric loss is improved by increasing the reduction degree. The optimized r-GONRs show ultrahigh electromagnetic absorption, up to -65.09 dB at a thickness of 2 mm, which is more advantageous than the reported values of other carbon materials. The efficient absorption bandwidth (reflection loss