• 文献标题:   Microwave-assisted preparation of novel graphene-like carbon material from waste bamboo for high-performance supercapacitors
  • 文献类型:   Article
  • 作  者:   WANG YH, WANG HH, CHEN YD, SRINIVASAKANNAN C, TANG RH, DUAN XH
  • 作者关键词:   bamboowaste, catalytic graphitization, microwaveassisted, graphenelike carbon material, supercapacitor
  • 出版物名称:   JOURNAL OF POROUS MATERIALS
  • ISSN:   1380-2224 EI 1573-4854
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1007/s10934-022-01350-x EA NOV 2022
  • 出版年:   2023

▎ 摘  要

Graphene-like carbon material was rapidly synthesized from waste bamboo stem as raw material with assistance of microwave heating and KHCO3 acting as both catalyst and activating agent. The graphene-like carbon material was composed of graphene-like nano sheets with high degree of graphitization, which had porous structure with specific surface area of 1887 m(2)/g. The product was evaluated as electrode material for supercapacitor and showed excellent electrochemical performance. At a current density of 0.5 A/g, the specific capacitance reached 204.0 F/g in the three-electrode system. After 10,000 cycles at 10.0 A/g current density, the maximum specific capacitance of a single electrode was 139.0 F/g, with the specific capacitance retention of 93.83%. While at a current density of 0.5 A/g, the maximum specific capacitance was 75.9 F/g in the coin-type symmetric supercapacitor, and after 5000 cycles at 10.0 A/g current density, the capacitance retention was 94.02%, showing a high capacitance retention. The experimental results indicated that microwave-assisted catalytic graphitization was a simple and fast process and it could potentially serve as an excellent green and low-cost methodology for preparation of graphene-like carbon material having good quality.