• 文献标题:   Superuniform Molecular Nanogate Fabrication on Graphene Sheets of Single Wall Carbon Nanohorns for Selective Molecular Separation of CO2 and CH4
  • 文献类型:   Article
  • 作  者:   OHBA T, KANOH H, KANEKO K
  • 作者关键词:  
  • 出版物名称:   CHEMISTRY LETTERS
  • ISSN:   0366-7022 EI 1348-0715
  • 通讯作者地址:   Chiba Univ
  • 被引频次:   16
  • DOI:   10.1246/cl.2011.1089
  • 出版年:   2011

▎ 摘  要

Superuniform nanosized gates (nanogates; 0.41 +/- 0.02 nm in size) were donated on graphene sheets of single wall carbon nanohorn (SWCNH) particles by controlled oxidation. Superuniform nanogate donation confers high molecular selectivity and large adsorption capacity upon SWCNH. The molecular selectivity of CO2 over CH4 attains 17 below 0.01 MPa by the nanogate separation.