• 文献标题:   Impedance Spectroscopy Analysis and Equivalent Circuit Modeling of Graphene Oxide Solutions
  • 文献类型:   Article
  • 作  者:   YOON Y, JO J, KIM S, LEE IG, CHO BJ, SHIN M, HWANG WS
  • 作者关键词:   graphene oxide solution, impedance spectroscopy analysi, equivalent circuit model
  • 出版物名称:   NANOMATERIALS
  • ISSN:   2079-4991
  • 通讯作者地址:   Korea Aerosp Univ
  • 被引频次:   2
  • DOI:   10.3390/nano7120446
  • 出版年:   2017

▎ 摘  要

The optical and electrical characteristics of a graphene oxide solution (GS) with different graphene oxide (GO) concentrations in de-ionized water are investigated via the electrochemical impedance spectroscopy (EIS) method. The measurement results produced by the EIS for the GS are represented with both Bode and Nyquist plots in a frequency range from 1 kHz to 10 MHz. Using these results, we develop an equivalent circuit model as a function of the GO concentration, representing the GS as a mixed circuit of two-dimensional (2D) GO dispersed in parallel in de-ionized (DI) water. The underlying physics of the current-flowing behavior in the GS are explained and interpreted using empirical circuit models; the circuit model also shows that highly resistive GO becomes conductive in GS form in the DI water. The findings in this work should draw new attention toward GSes and related applications, including functional composite materials, catalysts, and filter membranes.