• 文献标题:   Discharge Characteristic of Fluorinated Graphene-like Graphite as a Cathode of Lithium Primary Battery
  • 文献类型:   Article
  • 作  者:   MATSUO Y, INAMOTO J, YAMAMOTO H, MATSUMOTO K, HAGIWARA R
  • 作者关键词:   lithium primary battery, graphenelike graphite, fluorination
  • 出版物名称:   ELECTROCHEMISTRY
  • ISSN:   1344-3542 EI 2186-2451
  • 通讯作者地址:   Univ Hyogo
  • 被引频次:   0
  • DOI:   10.5796/electrochemistry.20-64068
  • 出版年:   2020

▎ 摘  要

Graphene-like graphite prepared by heating graphite oxide under vacuum at 800 degrees C was fluorinated by elemental fluorine in the presence of HF at room temperature. The interlayer spacing of the resulting material was 0.639 nm and it showed CxF type characteristics. The fluorine content of it (x = 1.7) was higher than that obtained from natural graphite (x = 2.3). The discharge capacity of it as a cathode of lithium primary battery reached 940 mAhg(-1) at a low current density, which was 50% larger than the theoretical capacity based on the 100% discharge of fluorine. (C) The Author(s) 2020. Published by ECSJ.