• 文献标题:   Toughening rubbers with a hybrid filler network of graphene and carbon nanotubes
  • 文献类型:   Article
  • 作  者:   LI HY, YANG L, WENG GS, XING W, WU JR, HUANG GS
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY A
  • ISSN:   2050-7488 EI 2050-7496
  • 通讯作者地址:   Sichuan Univ
  • 被引频次:   40
  • DOI:   10.1039/c5ta05836h
  • 出版年:   2015

▎ 摘  要

Unfilled rubbers usually show poor mechanical properties. Here, we demonstrate toughening natural rubber (NR) by designing a compact hybrid filler network composed of graphene (GE) and carbon nanotubes (CNTs). The physical interactions in this network have a bond energy lower than covalent bonds; and thus they preferentially break upon deformation and serve as sacrificial bonds that dissipate energy before failure of the materials. The high energy dissipation of the hybrid filler network not only increases the fracture toughness and tensile strength, but also suppresses the crack growth of the NR/GE/CNT nanocomposites. These properties will provide the nanocomposites with better sustainability during practical applications.