• 文献标题:   Graphene Quantum Dots Incorporated into beta-cyclodextrin: a Novel Polymeric Nanocomposite for Non-Enzymatic Sensing of L-Tyrosine at Physiological pH
  • 文献类型:   Article
  • 作  者:   SHADJOU N, HASANZADEH M, TALEBI F
  • 作者关键词:   ltyrosine, graphene quantum dot, physiological ph, betacyclodextrin, nanosensor, amino acid
  • 出版物名称:   JOURNAL OF ANALYTICAL CHEMISTRY
  • ISSN:   1061-9348 EI 1608-3199
  • 通讯作者地址:   Tabriz Univ Med Sci
  • 被引频次:   9
  • DOI:   10.1134/S1061934818060096
  • 出版年:   2018

▎ 摘  要

Graphene quantum dot-beta-cyclodextrin modified glassy carbon electrode was used as a new nanosensor for determination of L-tyrosine (L-Tyr). It was found that graphene quantum dot-beta-cyclodextrin has been stably electrodeposited on glassy carbon electrode modified by simple technique. The cyclic voltammograms of the modified electrode in an aqueous solution displayed a pair of well-defined, stable and irreversible reductive/oxidation redox systems. The apparent electron transfer rate constant (k (s)) and transfer coefficient (alpha) determined by cyclic voltammetry were approximately equal to 8.0 s(-1) and 0.7, respectively. The modified electrode showed excellent catalytic activity towards the oxidation of L-Tyr at positive potential in buffer solution. The nanosensor also displayed fast response time, high sensitivity, low detection limit and a remarkably positive potential oxidation of L-Tyr that decreased the effect of interferences in analysis.