• 文献标题:   Efficient visible light driven hydrogen generation using 9-(3,3-dimethyl-1,2-oxazetidine-N-yl)perylene-3,4-dicarboximide functionalized amino graphene
  • 文献类型:   Article
  • 作  者:   ABINAYA K, KARTHIKAIKUMAR S, SUDHA K, SUNDHARAMURTHI S, ELANGOVAN A, KALIMUTHU P
  • 作者关键词:   photocatalyst, pushpull perylene, perylenegraphene hybrid, hydrogen generation, sacrificial donor
  • 出版物名称:   APPLIED CATALYSIS BENVIRONMENTAL
  • ISSN:   0926-3373 EI 1873-3883
  • 通讯作者地址:   Gandhigram Rural Inst Deemed Be Univ
  • 被引频次:   3
  • DOI:   10.1016/j.apcatb.2018.09.098
  • 出版年:   2019

▎ 摘  要

Synthesis of oxazetidine substituted perylene dye N-(2,5-di-tert-butylphenyl)-9-(3,3-dimethyl-1,2-oxazetidine-N-yl)perylene-3,4-dicarboximide is reported. The imide moiety present in the reported dye was used to functionalize amino graphene. The 9-(3,3-dimethyl-1,2-oxazetidine-N-yl) perylene-3,4-dicarboximide was used as light harvester for photocatalytic hydrogen generation by covalently attaching on to amino graphene surface. The composite AG-DOPMI/Pt was prepared and found to be an efficient photocatalyts for hydrogen production from methanol:water mixture which can produce 1489 mu mol/g hydrogen. The oxazetidine dye gives rise to the production of hydrogen generation even in the absence of sacrificial donor.