• 文献标题:   Enhanced electrochemiluminescence from reduced graphene oxide-CdTe quantum dots for highly selective determination of copper ion
  • 文献类型:   Article
  • 作  者:   HU FX, WANG JL, CHEN SH, RAO QH
  • 作者关键词:   copper ion, electrochemiluminescence, rgocdte quantum dot, sensor
  • 出版物名称:   LUMINESCENCE
  • ISSN:   1522-7235 EI 1522-7243
  • 通讯作者地址:   Suzhou Univ Sci Technol
  • 被引频次:   1
  • DOI:   10.1002/bio.3649
  • 出版年:   2019

▎ 摘  要

An electrochemiluminescence (ECL) sensor based on reduced graphene oxide-CdTe quantum dots (RGO-CdTe QDs) composites for detecting copper ion (Cu2+) was proposed. The ECL behaviours of the RGO-CdTe QD modified electrode were investigated with H2O2 as the co-reactant. Quantitative detection of Cu2+ was realized as Cu2+ could effectively quench the ECL signal of the RGO-CdTe QDs. A wide linear range of 1.00 x 10(-14) to 1.00 x 10(-4) M (R = 0.9953) was obtained under optimized conditions, and a detection limit (S/N = 3) was achieved of as low as 3.33 x 10(-15) M. The proposed sensor also exhibited good stability and selectivity for the detection of copper ions. Finally, the analytical application of the proposed sensor was also evaluated using river water.