• 文献标题:   BN White Graphene with "Colorful" Edges: The Energies and Morphology
  • 文献类型:   Article
  • 作  者:   LIU YY, BHOWMICK S, YAKOBSON BI
  • 作者关键词:   boronnitride, graphene, edge, interface, bandgap, magnetism
  • 出版物名称:   NANO LETTERS
  • ISSN:   1530-6984
  • 通讯作者地址:   Rice Univ
  • 被引频次:   200
  • DOI:   10.1021/nl2011142
  • 出版年:   2011

▎ 摘  要

Interfaces play a key role in low dimensional materials like graphene or its boron nitrogen analog, white graphene. The edge energy of hexagonal boron nitride (h-BN) has not been determined as its lower symmetry makes it difficult to separate the opposite B-rich and N-rich zigzag sides. We report unambiguous energy values for arbitrary edges of BN, including the dependence on the elemental chemical potentials of B and N species. A useful manifestation of the additional Gibbs degree of freedom in the binary system, this dependence offers a way to control the morphology of pure BN or its carbon inclusions and to engineer their electronic and magnetic properties.