• 文献标题:   Remarkable high-temperature Li-storage performance of few-layer graphene-anchored Fe3O4 nanocomposites as an anode
  • 文献类型:   Article
  • 作  者:   HUANG MB, CHEN CH, WU SP, TIAN XD
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY A
  • ISSN:   2050-7488 EI 2050-7496
  • 通讯作者地址:   South China Univ Technol
  • 被引频次:   19
  • DOI:   10.1039/c7ta07364j
  • 出版年:   2017

▎ 摘  要

Herein, a novel and efficient strategy was established to synthesize few-layer graphene-anchored Fe3O4 nanocomposites (FLG-anchored Fe3O4) through a facile ball-milling route followed by annealing treatment. The as-prepared FLG-anchored Fe3O4 nanocomposites, as an anode material of LIBs, presented remarkable electrochemical performances at a high temperature of 85 degrees C, i.e., an excellent reversible capacity of 1413 mA h g(-1) at a current density of 1.0 A g(-1) after 100 cycles and an impressive rate performance of 768 mA h g(-1) at a large current density of 5.0 A g(-1) even after 100 cycles. These superior performances can be considered as a comprehensive consequence of the following factors: (1) the robust anchor between in situ synthesized Fe3O4 nanoparticles and few-layer graphene via a Fe-OC linkage maintains structural integrity, enabling excellent cycling stability even at high temperatures; (2) accelerated dynamic diffusion of Li+ ions during lithiation/delithiation at 85 degrees C leads to a decreased polarization effect, producing enhanced reversibility; (3) enhanced pseudocapacitive behaviour at high temperatures holds partial capacity contribution. Due to these attributes, this material is a reliable and promising candidate for an anode material for heavy-duty Li-ion batteries that operate under harsh environments.