• 文献标题:   Transformation of C-14-Labeled Graphene to (CO2)-C-14 in the Shoots of a Rice Plant
  • 文献类型:   Article
  • 作  者:   HUANG C, XIA T, NIU JF, YANG Y, LIN SJ, WANG XK, YANG GQ, MAO L, XING BS
  • 作者关键词:   carbon14, carbon dioxide, graphene, rice plant, uptake distribution
  • 出版物名称:   ANGEWANDTE CHEMIEINTERNATIONAL EDITION
  • ISSN:   1433-7851 EI 1521-3773
  • 通讯作者地址:   Nanjing Univ
  • 被引频次:   4
  • DOI:   10.1002/anie.201805099
  • 出版年:   2018

▎ 摘  要

This study focused on using carbon-14-labeled few-layer graphene (FLG) to determine its uptake, distribution, transformation, and depuration in rice plants. After 7d hydroponic exposure to FLG suspension at 250gL(-1), roots accumulated 694.8mgkg(-1) graphene and shoots had 53.7mgkg(-1) graphene from intra-plant translocation. FLG could likely pass through the cell wall and membrane and enter the chloroplast in the shoots. After 14 days of depuration, only about 15% of the accumulated FLG were eliminated into the depuration solution with about 70% of graphene retained in the plants. About 9% of the accumulated FLG was degraded to (CO2)-C-14 and proposed that reaction with OH. in the leaves may likely contribute to the degradation of FLG, which had structural defects. These findings have an important impact on the long-term environmental fate of graphene-related materials in soil-plant systems.